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Preparation and characterization of SO42-/TiO2 and S2O82-/TiO2 catalysts

MA Xuedan, GUO Daishi, JIANG Qizhong, MA Zifeng, MA Zhengfei, YE Weidong, LI Chunbo

Frontiers of Chemical Science and Engineering 2007, Volume 1, Issue 1,   Pages 45-49 doi: 10.1007/s11705-007-0009-5

Abstract: Nanosized solid superacids SO/TiO and SO/TiO, as well as MCM-41-supported SO/ZrO, were prepared.The results showed that SO/TiO and SO/TiO possess not only nanosized particles with diameters <7.0 nmDifferent from the Lewis acid nature of SO/ZrO/MCM-41, SO/TiO and SO/TiO exhibit mainly Br¢nsted aciditiesSO/TiO even stronger than those on SO/ZrO/MCM-41 were generated when persulfate solution was used asBecause of their distinct acid natures, SO/TiO and SO/TiO exhibited catalytic activities for the cyclization

Keywords： exhibit     Different     persulfate     adsorption-desorption     catalytic    

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Influence of surface modified mixed metal oxide nanoparticles on the electrochemical and mechanical properties of polyurethane matrix

Frontiers of Chemical Science and Engineering 2023, Volume 17, Issue 1,   Pages 1-14 doi: 10.1007/s11705-022-2176-9

Abstract: Newly synthesized functional nanoparticles, 3-amino-1,2,4-triazole (ATA)/SiO2–TiO2Rcoat) of PU–ATA/SiO2–TiO2 was determinedThe current measured along the scratched surface of the PU–ATA/SiO2–TiO2 coatingWater contact angle testing validated the hydrophobic nature of the PU–ATA/SiO2–TiO2SiO2−TiO2 nanoparticles was 2 wt %, dynamic mechanical

Keywords： SiO2/TiO2 nanoparticle     nanocomposite coatings     dynamic mechanical analysis     electrochemical    

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Preparation and rheological behaviors of PA6/SiO2 nanocompiste

WEI Shanshan, LIU Yuejun, LI Xianggang, HUANG Yugang, WANG Xiayu, ZHANG Ping

Frontiers of Chemical Science and Engineering 2007, Volume 1, Issue 4,   Pages 332-337 doi: 10.1007/s11705-007-0060-2

Abstract: The polyamide 6 (PA6)/SiO nanocomposites were prepared by in situ polymerization and the rheologicalThe results showed that the SiO particle size was around 50 nm and the particles dispersed evenly inapparent viscosities of nanocomposites increased initially and then decreased with the increase in nano-SiOWith the increase in nano-SiO content the apparent viscous activation energies of nanocomposites increasedrheological behaviors revealed that there were strong interactions between PA6 macromolecule chains and nano-SiO

Keywords： polyamide     temperature     rheological     activation     pesudoplastic    

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Hydrogenation of furfuryl alcohol to tetrahydrofurfuryl alcohol on NiB/SiO2 amorphous alloy catalyst

SONG Yun, LI Wei, ZHANG Minghui, TAO Keyi

Frontiers of Chemical Science and Engineering 2007, Volume 1, Issue 2,   Pages 151-154 doi: 10.1007/s11705-007-0028-2

Abstract: NiB/SiO amorphous alloy catalyst was prepared by power electroless plating method and characterized byThe catalytic performance of NiB/SiO was investigated for the hydrogenation of furfuryl alcohol (FA)

Keywords： following     Brunauer     electroless     temperature     transmission    

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Preparation of lignin/TiO2 nanocomposites and their application in aqueous polyurethane coatings

Dongjie Yang, Shengyu Wang, Ruisheng Zhong, Weifeng Liu, Xueqing Qiu

Frontiers of Chemical Science and Engineering 2019, Volume 13, Issue 1,   Pages 59-69 doi: 10.1007/s11705-018-1712-0

Abstract: A simple method using a water soluble lignin quaternary ammonium salt (LQAS) and TiO has been developedfor the preparation of lignin/TiO nanocomposites in an aqueous medium under mild conditions.The LQAS/TiO nanocomposites contain well-dispersed small particles with excellent ultraviolet (UV) shieldingWhen the LQAS/TiO nanocomposites were blended with WPU, the UV absorbance and the tensile ductilityThe composite WPU hybrid film containing 6 wt-% LQAS/TiO nanocomposite had the highest visible light

Keywords： lignin     TiO2     nanocomposite particle     polyurethane film    

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A method for improve the mechanical robustness of the superhydrophobic wood

Wang Chengyu and Liu Feng

Strategic Study of CAE 2014, Volume 16, Issue 4,   Pages 79-82

Abstract: repellency and corrosion resistance.We have investigated a fabrication of polyvinyl alcohol（PVA）/silica（SiO2

Keywords： superhydrophobic     mechanical robustness     PVA/SiO2     wood surface    

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Plasmonic Au nanoparticles supported on both sides of TiO2 hollow spheres for maximising photocatalytic

Jianwei Lu, Lan Lan, Xiaoteng Terence Liu, Na Wang, Xiaolei Fan

Frontiers of Chemical Science and Engineering 2019, Volume 13, Issue 4,   Pages 665-671 doi: 10.1007/s11705-019-1815-2

Abstract: A strategy of intensifying the visible light harvesting ability of anatase TiO hollow spheres (HSs)was developed, in which both sides of TiO HSs were utilised for stabilising Au nanoparticles (NPs) throughThe composite structure of single Au NP yolk-TiO shell-Au NPs, denoted as Au@Au(TiO , was rendered andAu@Au(TiO showed enhanced photocatalytic activity in the degradation of methylene blue and phenol inaqueous phase under visible light surpassing that of other reference materials such as Au(TiO by 77%

Keywords： TiO2 hollow spheres     plasmonic Au nanoparticles     confinement     visible light     photocatalytic degradation    

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Fabrication of superhydrophobic SiO2/PS coatings on wood surface

Zhang Ming and Wang Chengyu

Strategic Study of CAE 2014, Volume 16, Issue 4,   Pages 83-86

Abstract:

The silica particles with unique morphology and hydrophobicity have been synthesized via a one-step sol-gel process，which as well as polystyrene was employed in the bionic and stably superhydrophobic coatings with water contact angle of 153° and sliding angle less than 5° on wood surface by a drop-coating method. Scanning electron microscope (SEM) studies revealed that the composite coatings possess two dimensional hierarchical structures comprising of micron scale papilla and submicron scale granules. The synergistic effect of micron/submicron binary structure and low surface energy layer was responsible for the superhydrophobicity of wood surface. Moreover，the stability and durability of treated wood have been investigated as well，and the results showed that the product possesses superhydrophobic property in a wide extent，such as pure water，corrosive water under both acidic and basic conditions，some common organic solvents，which offers an opportunity to extend the range of practical applications for wood resources.

Keywords： superhydrophobic     wood surface     drop-coating method     composite coatings    

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Preparation and properties of nano SiO2 core-shell structured additives and their nanocomposite with

KE Yangchuan, SUN Mingzhuo, SONG Yanxin, YANG GuangFu

Frontiers of Chemical Science and Engineering 2007, Volume 1, Issue 1,   Pages 76-80 doi: 10.1007/s11705-007-0016-6

Abstract: compatibility with other additives, as well as to solve complex problems in practical applications, SiOAs a result, the prepared composite additive the nanoparticle precursor (NPP0) produces excellent results

Keywords： deformation coefficient     distortion temperature     excellent     NPP0-PP     traditional nucleation    

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Synthesis of TiO2 nano-particles and their photocatalytic activity for formaldehyde and methyl orange

XIAO Xinyan, ZHANG Huiping, CHEN Huanqin, LIAO Dongliang

Frontiers of Chemical Science and Engineering 2007, Volume 1, Issue 2,   Pages 178-183 doi: 10.1007/s11705-007-0033-5

Abstract: TiO nano-particles were synthesized by sol-gel technique and characterized by X-ray diffractometer (XRDBased on the orthogonal test results, the optimal condition for TiO preparation was obtained.Results showed that particle sizes were in the range of 10 40 nm, and that prepared TiO had better photocatalytic

Keywords： prepared     photocatalytic activity     apparent     photocatalytic     orthogonal    

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Solar photocatalytic decomposition of two azo dyes on multi-walled carbon nanotubes (MWCNTs)/TiO 2 composites

Huilong WANG, Shuqin LIU, Hui WANG, Wenfeng JIANG,

Frontiers of Environmental Science & Engineering 2010, Volume 4, Issue 3,   Pages 311-320 doi: 10.1007/s11783-010-0237-7

Abstract: Multi-walled carbon nanotubes (MWCNTs)/TiO composite photocatalysts with high photoactivity were preparedCompared to pure TiO, the combination of MWCNTs with titania could cause a significant absorption shiftThe photocatalytic performances of the MWCNTs/TiO composite catalysts were evaluated for the decompositionThe results showed that the addition of MWCNTs enhanced the adsorption and photocatalytic activity of TiO

Keywords： sol-gel     multi-walled carbon nanotubes (MWCNTs)/TiO2 composite     photocatalysis     azo dye     solar irradiation    

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Applied study on pyrolysis of bisphenol A diphosphate flame-retarded ABS

Xu Xiaonan,Lu Lingang,Chen Nan,Yin Quanming,Wang Dawei

Strategic Study of CAE 2010, Volume 12, Issue 2,   Pages 62-69

Abstract: UL94), flame retardant performances, smoke release of bisphenol A diphosphate (BDP), BDP/APP and BDP/SiO2 added in ABS are studied.Adding BDP//NP / SiO2 =20 %/5 %/7 %BDP into ABS resin, its impact strength increased by 20.00ABS resin added BDP/NP (20 %/5 %) and nanometer SiO2(7 %) has the best flame retarded and

Keywords： BDP     ABS     APP     SiO2     flame retardant     smoke    

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Investigation of the effects of humic acid and H 2 O 2 on the photocatalytic degradation of atrazine

Chao QIN, Shaogui YANG, Cheng SUN, Jia ZHOU, Manjun ZHAN, Rongjun WANG, Huanxing CAI,

Frontiers of Environmental Science & Engineering 2010, Volume 4, Issue 3,   Pages 321-328 doi: 10.1007/s11783-010-0238-6

Abstract: A solution of atrazine in a TiO suspension, an endocrine disruptor in natural water, was tentatively

Keywords： atrazine     retardation effect     photocatalysis     TiO2    

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The stabilization effect of Al2O3 on unconventional Pb/SiO2 catalyst

Frontiers of Chemical Science and Engineering 2023, Volume 17, Issue 10,   Pages 1423-1429 doi: 10.1007/s11705-023-2315-y

Abstract: To enhance the stability, the traditional carrier Al2O3 with a small amount, wasintroduced into Pb/SiO2 catalyst in this study.It has been proved that Al2O3 can inhibit the reduction of PbO, and weaken theAs a result, 3Al15Pb/SiO2 catalyst exhibits a much higher stability up to more than 150 h.addition, a simple schematic diagram of the change of surface species on the catalyst surface after Al2<

Keywords： Pb/SiO2     Al2O3     propane dehydrogenation     propene     stability    

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Effect of TiO 2 loading on the activity of V/TiO 2 -Al 2 O 3 in the catalytic oxidehydrogenation of ethylbenzene

Xiaohong LI, Wenying LI,

Frontiers of Chemical Science and Engineering 2010, Volume 4, Issue 2,   Pages 142-146 doi: 10.1007/s11705-009-0233-2

Abstract: TiO-AlOmixed oxides with different compositions ranging from 40wt-% to 95wt-% of TiO were prepared byTiO content in the support had obvious effect on the crystal structure, texture characteristic, acidThe highest catalytic activity was acquired when the TiO content was 50 wt-%.

Keywords： desorption     different     TiO-AlOmixed     physisorption     ethylbenzene    

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Title Author Date Type Operation

Preparation and characterization of SO42-/TiO2 and S2O82-/TiO2 catalysts

MA Xuedan, GUO Daishi, JIANG Qizhong, MA Zifeng, MA Zhengfei, YE Weidong, LI Chunbo

Journal Article

Influence of surface modified mixed metal oxide nanoparticles on the electrochemical and mechanical properties of polyurethane matrix

Journal Article

Preparation and rheological behaviors of PA6/SiO2 nanocompiste

WEI Shanshan, LIU Yuejun, LI Xianggang, HUANG Yugang, WANG Xiayu, ZHANG Ping

Journal Article

Hydrogenation of furfuryl alcohol to tetrahydrofurfuryl alcohol on NiB/SiO2 amorphous alloy catalyst

SONG Yun, LI Wei, ZHANG Minghui, TAO Keyi

Journal Article

Preparation of lignin/TiO2 nanocomposites and their application in aqueous polyurethane coatings

Dongjie Yang, Shengyu Wang, Ruisheng Zhong, Weifeng Liu, Xueqing Qiu

Journal Article

A method for improve the mechanical robustness of the superhydrophobic wood

Wang Chengyu and Liu Feng

Journal Article

Plasmonic Au nanoparticles supported on both sides of TiO2 hollow spheres for maximising photocatalytic

Jianwei Lu, Lan Lan, Xiaoteng Terence Liu, Na Wang, Xiaolei Fan

Journal Article

Fabrication of superhydrophobic SiO2/PS coatings on wood surface

Zhang Ming and Wang Chengyu

Journal Article

Preparation and properties of nano SiO2 core-shell structured additives and their nanocomposite with

KE Yangchuan, SUN Mingzhuo, SONG Yanxin, YANG GuangFu

Journal Article

Synthesis of TiO2 nano-particles and their photocatalytic activity for formaldehyde and methyl orange

XIAO Xinyan, ZHANG Huiping, CHEN Huanqin, LIAO Dongliang

Journal Article

Solar photocatalytic decomposition of two azo dyes on multi-walled carbon nanotubes (MWCNTs)/TiO 2 composites

Huilong WANG, Shuqin LIU, Hui WANG, Wenfeng JIANG,

Journal Article

Applied study on pyrolysis of bisphenol A diphosphate flame-retarded ABS

Xu Xiaonan,Lu Lingang,Chen Nan,Yin Quanming,Wang Dawei

Journal Article

Investigation of the effects of humic acid and H 2 O 2 on the photocatalytic degradation of atrazine

Chao QIN, Shaogui YANG, Cheng SUN, Jia ZHOU, Manjun ZHAN, Rongjun WANG, Huanxing CAI,

Journal Article

The stabilization effect of Al2O3 on unconventional Pb/SiO2 catalyst

Journal Article

Effect of TiO 2 loading on the activity of V/TiO 2 -Al 2 O 3 in the catalytic oxidehydrogenation of ethylbenzene

Xiaohong LI, Wenying LI,

Journal Article